$1. 首先分析CaO_{2}与H_{2}O反应的化学方程式:$
$已知2Na_{2}O_{2}+2H_{2}O = 4NaOH + O_{2}\uparrow,CaO_{2}与Na_{2}O_{2}化学性质相似。$
$根据质量守恒定律(原子种类和数目不变),2CaO_{2}+2H_{2}O = 2Ca(OH)_{2}+O_{2}\uparrow。$
$2. 然后计算样品中CaO_{2}的质量分数:$
$解:设20g样品中CaO_{2}的质量为x。$
$化学方程式为2CaO_{2}+2H_{2}O = 2Ca(OH)_{2}+O_{2}\uparrow。$
$列出比例式:$
$CaO_{2}的相对分子质量M = 40 + 16×2=72,O_{2}的相对分子质量M = 16×2 = 32。$
$由2CaO_{2}+2H_{2}O = 2Ca(OH)_{2}+O_{2}\uparrow可得\frac{2×72}{32}=\frac{x}{3.2g}。$
$交叉相乘得32x = 2×72×3.2g。$
$解得x=\frac{2×72×3.2g}{32}=14.4g。$
$计算CaO_{2}的质量分数\omega:$
$\omega=\frac{14.4g}{20g}×100\% = 72\%。$
$综上,(1)O_{2}\uparrow;(2)该样品中CaO_{2}的质量分数为72\%。$