解:(1)$\because ∠FOD=21°,$$∠AOE=2∠FOD,$
$\therefore ∠AOE=42°,$
$\because ∠AOE+∠BOE=180°,$
$\therefore ∠BOE=180°-42°=138°,$
$\because OC$平分$∠BOE,$
$\therefore ∠BOC=\frac{1}{2}∠BOE=69°,$
$\because ∠AOD$与$∠BOC$是对顶角,
$\therefore ∠AOD=∠BOC=69°。$
(2)$OE⊥ OF,$理由如下:
设$∠FOD=α,$则$∠AOE=2α,$
$\because ∠AOE+∠BOE=180°,$
$\therefore ∠BOE=180°-2α,$
$\because OC$平分$∠BOE,$
$\therefore ∠BOC=\frac{1}{2}∠BOE=90°-α,$
$\because ∠EOD$与$∠BOC$是对顶角,
$\therefore ∠EOD=∠BOC=90°-α,$
$\therefore ∠EOF=∠EOD+∠FOD=90°-α+α=90°,$
$\therefore OE⊥ OF。$