解:连接 $OC, BC。$
$\because ∠ ACD = 120°,$$AC = CD,$
$\therefore ∠ CAD = ∠ D = \frac{180° - 120°}{2} = 30°。$
$\because AB$ 是 $\odot O$ 的直径,
$\therefore ∠ ACB = 90°,$
$\therefore ∠ ABC = 60°。$
$\because OC = OB,$
$\therefore △ OBC$ 是等边三角形,
$\therefore ∠ COB = 60°,$
$\therefore S_{\mathrm{扇形}OCB} = \frac{60π × 2^2}{360} = \frac{2}{3}π。$
$\because ∠ D = 30°,$
$\therefore ∠ OCD = 90°,$
$\therefore OD = 2OC = 4,$
$\therefore CD = \sqrt{4^2 - 2^2} = 2\sqrt{3},$
$\therefore S_{△ OCD} = \frac{1}{2} × 2 × 2\sqrt{3} = 2\sqrt{3},$
$\therefore S_{\mathrm{阴影部分}} = S_{△ OCD} - S_{\mathrm{扇形}OCB} = 2\sqrt{3} - \frac{2}{3}π。$