证明: (1)∵四边形ABCD是平行四边形,
∴AD=BC,AD//BC.
∵BE=DF,
∴AD-DF=BC-BE,即AF=EC.
∴四边形AECF是平行四边形.
∵AC=EF,
∴四边形AECF是矩形.
(2)∵四边形AECF是矩形,
∴∠AEC=∠AEB=90°.
∴在Rt△AEB中,$AE^2 + BE^2 = AB^2$.
∵AE=BE,AB=2,
∴$AE^2 + AE^2 = 4$.
∴$AE = \sqrt{2} = BE$.
∵在Rt△AEC中,$\tan\angle ACB = \frac{AE}{EC} = \frac{1}{2},$
∴$EC = 2AE = 2\sqrt{2}$.
∴$BC = BE + EC = \sqrt{2} + 2\sqrt{2} = 3\sqrt{2}$