解:生成二氧化碳的质量为$2.0\mathrm {g} + 21.64\mathrm {g} - 23.2\mathrm {g} = 0.44\mathrm {g}。$
设每片钙片中碳酸钙的质量为$x,$生成氯化钙的质量为$y。$
${\mathrm {CaCO}_{3} + 2\mathrm {HCl} \xlongequal{} \mathrm {CaCl}_{2} + \mathrm {H}_{2}\mathrm {O} + \mathrm {CO}_{2}↑}$
100 111 44
$x$ y 0.44g
$\frac {100}{44}=\frac {x}{0.44\mathrm {g}},$解得$x = 1.0\mathrm {g}$
$\frac {111}{44}=\frac {y}{0.44\mathrm {g}},$解得$y = 1.11\mathrm {g}$
所得溶液的质量为$1.0\mathrm {g} + 21.64\mathrm {g} - 0.44\mathrm {g} = 22.2\mathrm {g}。$
所得溶液的溶质质量分数为$\frac {1.11\mathrm {g}}{22.2\mathrm {g}}×100\% = 5.0\%。$
答:$(1\mathrm {)}$每片钙片中碳酸钙的质量为$1.0\mathrm {g};$$(2\mathrm {)}$所得溶液的溶质质量分数为$5.0\%。$