(1)证明:$\because CF// AB,$
$\therefore ∠ DAE=∠ CFE,$
$\because E$是$CD$的中点,
$\therefore DE=CE,$
在$△ ADE$和$△ FCE$中,
$\begin{cases}∠ DAE=∠ CFE\\∠ AED=∠ FEC\\DE=CE\end{cases},$
$\therefore △ ADE≌△ FCE(\mathrm{AAS})。$
(2)解:$\because E$是$CD$的中点,$DE=2,$
$\therefore CD=2DE=4,$
$\because$ 在$\mathrm{Rt}△ ACB$中,$∠ ACB=90°,$
$D$是$AB$的中点,
$\therefore CD=BD=\frac{1}{2}AB,$
$\because CF// AB,$$∠ DCF=120°,$
$\therefore ∠ CDB=180°-∠ DCF=60°,$
$\therefore △ BCD$是等边三角形,
$\therefore BC=CD=4。$