解: ∵$x=\frac {1}{5-2\sqrt {6}}=\frac {5+2\sqrt {6}}{(5-2\sqrt {6})(5+2\sqrt {6})}=5+2\sqrt {6},$
$ y=\frac {1}{5+2\sqrt {6}}=\frac {5-2\sqrt {6}}{(5+2\sqrt {6})(5-2\sqrt {6})}=5-2\sqrt {6},$
∴$x+y=10,$$xy=(5+2\sqrt {6})(5-2\sqrt {6})=25-24=1$
$ $原式$=\frac {x^2+y^2}{xy}-4=\frac {(x+y)^2-2xy}{xy}-4$
$ =\frac {10^2-2×1}{1}-4=100-2-4=94$