$解:①根据题意得,x=2时,x²+mx-n=0$
$把x=2代入x²+mx-n=0,得2²+2m-n=0$
$∴.2m-n=-4$
$∴ \frac{9^m}{3^n} =3^{2m-n}=3^{-4}= \frac{1}{3^4} = \frac{1}{81}$
$②根据题意得,x=2和x=-1时$
$x⁴+mx³+nx-16=0$
$把x=2和x=-1代入$
$得\begin{cases}{16+8m+2n-16=0}\\{1-m-n-16=0}\end{cases}$
$∴ \begin{cases}{m=5}\\{n=-20}\end{cases}$
$∴mn=-100.$