解:(1)$CG$与$C'G$的数量关系为:
$CG = C'G$,理由:
由题意:$BC = BC'$,
∵四边形$ABCD$为矩形,
∴$∠C = 90°$,
∵$C'G⊥BC'$,
∴$∠BC'G = 90°$,
∴$∠C = ∠BC'G = 90°$,
在$Rt△ BC'G$和$Rt△ BCG$中,
$\{\begin {array}{l} BC' = BC\\BG = BG\end {array} $,
∴$Rt△ BC'G≌Rt△ BCG(\mathrm {HL})$,
∴$C'G = CG$.
(2)由题意:$BC = BC' = 10$,
∵四边形$ABCD$为矩形,
∴$AB = CD = 6$,$AD = BC = 10$,
$∠A = ∠D = 90°$,
∴$AC' = \sqrt {BC'^2-AB^2}=\sqrt {10^2-6^2} = 8$.
∴$C'D = AD - AC' = 2$.
∵$∠AC'B + ∠ABC' = 90°$,
$∠AC'B + ∠DC'G = 90°$,
∴$∠ABC' = ∠DC'G$,
∵$∠A = ∠D = 90°$,
∴$△ ABC'∽△ DC'G$,
∴$\frac {AB}{AC'}=\frac {C'D}{GD}$,
∴$\frac {6}{8}=\frac {2}{GD}$,
∴$GD = \frac {8}{3}$,
∴$CG = CD - DG = \frac {10}{3}$.