解:$\because ∠ ACB=90°,$D是边AB的中点,
$\therefore ∠ A + ∠ B = 90°,$$CD=AD,$
$\therefore ∠ A = ∠ ACD。$
$\because CD$是折痕,
$\therefore ∠ ACD = ∠ DCE,$$∠ A = ∠ E。$
$\because CE ⊥ AB,$
$\therefore ∠ BCE + ∠ B = 90°,$
$\therefore ∠ BCE = ∠ A,$
$\therefore ∠ BCE = ∠ ACD = ∠ DCE = \frac{1}{3}∠ ACB = 30°,$
$\therefore ∠ E = ∠ A = 30°$